[The] reaction of nitrogen atoms with propane
Institution: | McGill University |
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Department: | Department of Physical Chemistry. |
Degree: | PhD |
Year: | 1952 |
Keywords: | Physical Chemistry. |
Record ID: | 1491205 |
Full text PDF: | http://digitool.library.mcgill.ca/thesisfile107471.pdf |
The reaction of nitrogen atoms with propane has been found to produce hydrogen cyanide, ethane, ethylene, methane and hydrogen in the temperature range 75c. – 292c. The rate of hydrogen cyanide formation at a constant nitrogen atom flow rate increased with increasing propane flow rate; no corresponding increase was observed for the rates of formation of the other hydrocarbons. Second order specific rate constants were calculated from the rates of disappearance of propane.